data_F6C
#

_chem_comp.id                                   F6C
_chem_comp.name                                 "Chlorophyll F"
_chem_comp.type                                 NON-POLYMER
_chem_comp.pdbx_type                            HETAIN
_chem_comp.formula                              "C55 H68 Mg N4 O6"
_chem_comp.mon_nstd_parent_comp_id              ?
_chem_comp.pdbx_synonyms                        "[methyl 9-ethenyl-14-ethyl-8-formyl-4,13,18-trimethyl-20-oxo-3-{3-oxo-3-[(3,7,11,15-tetramethylhexadec-2-en-1-yl)oxy]propyl}-3,4,23,25-tetradehydro-24,26-dihydrophorbine-21-carboxylatato(2-)-kappa~4~N~23~,N~24~,N~25~,N~26~]magnesium"
_chem_comp.pdbx_formal_charge                   0
_chem_comp.pdbx_initial_date                    2019-07-03
_chem_comp.pdbx_modified_date                   2021-03-13
_chem_comp.pdbx_ambiguous_flag                  N
_chem_comp.pdbx_release_status                  REL
_chem_comp.pdbx_replaced_by                     ?
_chem_comp.pdbx_replaces                        ?
_chem_comp.formula_weight                       905.457
_chem_comp.one_letter_code                      ?
_chem_comp.three_letter_code                    F6C
_chem_comp.pdbx_model_coordinates_details       ?
_chem_comp.pdbx_model_coordinates_missing_flag  Y
_chem_comp.pdbx_ideal_coordinates_details       Corina
_chem_comp.pdbx_ideal_coordinates_missing_flag  Y
_chem_comp.pdbx_model_coordinates_db_code       ?
_chem_comp.pdbx_subcomponent_list               ?
_chem_comp.pdbx_processing_site                 RCSB
#   #
loop_
_chem_comp_atom.comp_id
_chem_comp_atom.atom_id
_chem_comp_atom.alt_atom_id
_chem_comp_atom.type_symbol
_chem_comp_atom.charge
_chem_comp_atom.pdbx_align
_chem_comp_atom.pdbx_aromatic_flag
_chem_comp_atom.pdbx_leaving_atom_flag
_chem_comp_atom.pdbx_stereo_config
_chem_comp_atom.model_Cartn_x
_chem_comp_atom.model_Cartn_y
_chem_comp_atom.model_Cartn_z
_chem_comp_atom.pdbx_model_Cartn_x_ideal
_chem_comp_atom.pdbx_model_Cartn_y_ideal
_chem_comp_atom.pdbx_model_Cartn_z_ideal
_chem_comp_atom.pdbx_component_atom_id
_chem_comp_atom.pdbx_component_comp_id
_chem_comp_atom.pdbx_ordinal
F6C  CAA  C1   C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CAA  F6C    1  
F6C  CAB  C2   C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CAB  F6C    2  
F6C  CAC  C3   C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CAC  F6C    3  
F6C  CAD  C4   C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CAD  F6C    4  
F6C  NA   N1   N   0  1  N  N  S  ?  ?  ?  ?  ?  ?  NA   F6C    5  
F6C  CBA  C5   C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CBA  F6C    6  
F6C  CBB  C6   C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CBB  F6C    7  
F6C  CBC  C7   C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CBC  F6C    8  
F6C  CBD  C8   C   0  1  N  N  R  ?  ?  ?  ?  ?  ?  CBD  F6C    9  
F6C  NB   N2   N   0  1  N  N  N  ?  ?  ?  ?  ?  ?  NB   F6C   10  
F6C  OBD  O1   O   0  1  N  N  N  ?  ?  ?  ?  ?  ?  OBD  F6C   11  
F6C  CGA  C9   C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CGA  F6C   12  
F6C  CGD  C10  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CGD  F6C   13  
F6C  ND   N3   N   0  1  N  N  N  ?  ?  ?  ?  ?  ?  ND   F6C   14  
F6C  CED  C11  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CED  F6C   15  
F6C  CHA  C12  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CHA  F6C   16  
F6C  CHB  C13  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CHB  F6C   17  
F6C  CHC  C14  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CHC  F6C   18  
F6C  CHD  C15  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CHD  F6C   19  
F6C  CMA  C16  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CMA  F6C   20  
F6C  CMB  C17  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CMB  F6C   21  
F6C  CMC  C18  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CMC  F6C   22  
F6C  CMD  C19  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  CMD  F6C   23  
F6C  OMB  O2   O   0  1  N  N  N  ?  ?  ?  ?  ?  ?  OMB  F6C   24  
F6C  C1   C20  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C1   F6C   25  
F6C  C1A  C21  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C1A  F6C   26  
F6C  C1B  C22  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C1B  F6C   27  
F6C  C1C  C23  C   0  1  Y  N  N  ?  ?  ?  ?  ?  ?  C1C  F6C   28  
F6C  C1D  C24  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C1D  F6C   29  
F6C  O1A  O3   O   0  1  N  N  N  ?  ?  ?  ?  ?  ?  O1A  F6C   30  
F6C  O1D  O4   O   0  1  N  N  N  ?  ?  ?  ?  ?  ?  O1D  F6C   31  
F6C  C2   C25  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C2   F6C   32  
F6C  C2A  C26  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C2A  F6C   33  
F6C  C2B  C27  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C2B  F6C   34  
F6C  C2C  C28  C   0  1  Y  N  N  ?  ?  ?  ?  ?  ?  C2C  F6C   35  
F6C  C2D  C29  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C2D  F6C   36  
F6C  O2A  O5   O   0  1  N  N  N  ?  ?  ?  ?  ?  ?  O2A  F6C   37  
F6C  O2D  O6   O   0  1  N  N  N  ?  ?  ?  ?  ?  ?  O2D  F6C   38  
F6C  C3   C30  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C3   F6C   39  
F6C  C3A  C31  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C3A  F6C   40  
F6C  C3B  C32  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C3B  F6C   41  
F6C  C3C  C33  C   0  1  Y  N  N  ?  ?  ?  ?  ?  ?  C3C  F6C   42  
F6C  C3D  C34  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C3D  F6C   43  
F6C  C4   C35  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C4   F6C   44  
F6C  C4A  C36  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C4A  F6C   45  
F6C  C4B  C37  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C4B  F6C   46  
F6C  C4C  C38  C   0  1  Y  N  N  ?  ?  ?  ?  ?  ?  C4C  F6C   47  
F6C  C4D  C39  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C4D  F6C   48  
F6C  C5   C40  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C5   F6C   49  
F6C  C6   C41  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C6   F6C   50  
F6C  C7   C42  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C7   F6C   51  
F6C  C8   C43  C   0  1  N  N  R  ?  ?  ?  ?  ?  ?  C8   F6C   52  
F6C  C9   C44  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C9   F6C   53  
F6C  C10  C45  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C10  F6C   54  
F6C  C11  C46  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C11  F6C   55  
F6C  C12  C47  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C12  F6C   56  
F6C  C13  C48  C   0  1  N  N  R  ?  ?  ?  ?  ?  ?  C13  F6C   57  
F6C  C14  C49  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C14  F6C   58  
F6C  C15  C50  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C15  F6C   59  
F6C  NC   N4   N   0  1  Y  N  N  ?  ?  ?  ?  ?  ?  NC   F6C   60  
F6C  MG   MG1  MG  0  0  N  N  N  ?  ?  ?  ?  ?  ?  MG   F6C   61  
F6C  H1   H1   H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H1   F6C   62  
F6C  H2   H2   H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H2   F6C   63  
F6C  H3   H3   H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H3   F6C   64  
F6C  H4   H4   H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H4   F6C   65  
F6C  H5   H5   H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H5   F6C   66  
F6C  H6   H6   H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H6   F6C   67  
F6C  H7   H7   H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H7   F6C   68  
F6C  H8   H8   H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H8   F6C   69  
F6C  H9   H9   H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H9   F6C   70  
F6C  H10  H10  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H10  F6C   71  
F6C  H11  H11  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H11  F6C   72  
F6C  H12  H12  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H12  F6C   73  
F6C  H13  H13  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H13  F6C   74  
F6C  H14  H14  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H14  F6C   75  
F6C  H15  H15  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H15  F6C   76  
F6C  H16  H16  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H16  F6C   77  
F6C  H17  H17  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H17  F6C   78  
F6C  H18  H18  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H18  F6C   79  
F6C  H19  H19  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H19  F6C   80  
F6C  H20  H20  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H20  F6C   81  
F6C  H21  H21  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H21  F6C   82  
F6C  H22  H22  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H22  F6C   83  
F6C  H23  H23  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H23  F6C   84  
F6C  H24  H24  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H24  F6C   85  
F6C  H25  H25  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H25  F6C   86  
F6C  H26  H26  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H26  F6C   87  
F6C  H27  H27  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H27  F6C   88  
F6C  H28  H28  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H28  F6C   89  
F6C  H29  H29  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H29  F6C   90  
F6C  H30  H30  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H30  F6C   91  
F6C  H31  H31  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H31  F6C   92  
F6C  H32  H32  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H32  F6C   93  
F6C  H33  H33  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H33  F6C   94  
F6C  H34  H34  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H34  F6C   95  
F6C  H35  H35  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H35  F6C   96  
F6C  H36  H36  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H36  F6C   97  
F6C  H37  H37  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H37  F6C   98  
F6C  H38  H38  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H38  F6C   99  
F6C  H39  H39  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H39  F6C  100  
F6C  H40  H40  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H40  F6C  101  
F6C  H41  H41  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H41  F6C  102  
F6C  H42  H42  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H42  F6C  103  
F6C  H43  H43  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H43  F6C  104  
F6C  H44  H44  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H44  F6C  105  
F6C  H45  H45  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H45  F6C  106  
F6C  H46  H46  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H46  F6C  107  
F6C  H47  H47  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H47  F6C  108  
F6C  H48  H48  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H48  F6C  109  
F6C  H49  H49  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H49  F6C  110  
F6C  H50  H50  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H50  F6C  111  
F6C  H51  H51  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H51  F6C  112  
F6C  H52  H52  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H52  F6C  113  
F6C  H53  H53  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H53  F6C  114  
F6C  H54  H54  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H54  F6C  115  
F6C  H55  H55  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H55  F6C  116  
F6C  H56  H56  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H56  F6C  117  
F6C  H57  H57  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H57  F6C  118  
F6C  C16  C51  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C16  F6C  119  
F6C  C17  C52  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C17  F6C  120  
F6C  C18  C53  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C18  F6C  121  
F6C  C19  C54  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C19  F6C  122  
F6C  C20  C55  C   0  1  N  N  N  ?  ?  ?  ?  ?  ?  C20  F6C  123  
F6C  H58  H58  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H58  F6C  124  
F6C  H59  H59  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H59  F6C  125  
F6C  H60  H60  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H60  F6C  126  
F6C  H61  H61  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H61  F6C  127  
F6C  H62  H62  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H62  F6C  128  
F6C  H63  H63  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H63  F6C  129  
F6C  H64  H64  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H64  F6C  130  
F6C  H65  H65  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H65  F6C  131  
F6C  H66  H66  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H66  F6C  132  
F6C  H67  H67  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H67  F6C  133  
F6C  H68  H68  H   0  1  N  N  N  ?  ?  ?  ?  ?  ?  H68  F6C  134  
#   #
loop_
_chem_comp_bond.comp_id
_chem_comp_bond.atom_id_1
_chem_comp_bond.atom_id_2
_chem_comp_bond.value_order
_chem_comp_bond.pdbx_aromatic_flag
_chem_comp_bond.pdbx_stereo_config
_chem_comp_bond.pdbx_ordinal
F6C  CAA  CBA  SING  N  N    1  
F6C  CAA  C2A  SING  N  N    2  
F6C  CAB  CBB  DOUB  N  N    3  
F6C  CAB  C3B  SING  N  N    4  
F6C  CAC  CBC  SING  N  N    5  
F6C  CAC  C3C  SING  N  N    6  
F6C  CAD  CBD  SING  N  N    7  
F6C  CAD  OBD  DOUB  N  N    8  
F6C  CAD  C3D  SING  N  N    9  
F6C  NA   C1A  SING  N  N   10  
F6C  NA   C4A  SING  N  N   11  
F6C  NA   MG   SING  N  N   12  
F6C  CBA  CGA  SING  N  N   13  
F6C  CBD  CGD  SING  N  N   14  
F6C  CBD  CHA  SING  N  N   15  
F6C  NB   C1B  DOUB  N  N   16  
F6C  NB   C4B  SING  N  N   17  
F6C  NB   MG   SING  N  N   18  
F6C  CGA  O1A  DOUB  N  N   19  
F6C  CGA  O2A  SING  N  N   20  
F6C  CGD  O1D  DOUB  N  N   21  
F6C  CGD  O2D  SING  N  N   22  
F6C  ND   C1D  SING  N  N   23  
F6C  ND   C4D  DOUB  N  N   24  
F6C  ND   MG   SING  N  N   25  
F6C  CED  O2D  SING  N  N   26  
F6C  CHA  C1A  DOUB  N  N   27  
F6C  CHA  C4D  SING  N  N   28  
F6C  CHB  C1B  SING  N  N   29  
F6C  CHB  C4A  DOUB  N  N   30  
F6C  CHC  C1C  SING  N  N   31  
F6C  CHC  C4B  DOUB  N  N   32  
F6C  CHD  C1D  DOUB  N  N   33  
F6C  CHD  C4C  SING  N  N   34  
F6C  CMA  C3A  SING  N  N   35  
F6C  CMB  OMB  DOUB  N  N   36  
F6C  CMB  C2B  SING  N  N   37  
F6C  CMC  C2C  SING  N  N   38  
F6C  CMD  C2D  SING  N  N   39  
F6C  C1   C2   SING  N  N   40  
F6C  C1   O2A  SING  N  N   41  
F6C  C1A  C2A  SING  N  N   42  
F6C  C1B  C2B  SING  N  N   43  
F6C  C1C  C2C  DOUB  Y  N   44  
F6C  C1C  NC   SING  Y  N   45  
F6C  C1D  C2D  SING  N  N   46  
F6C  C2   C3   DOUB  N  E   47  
F6C  C2A  C3A  DOUB  N  N   48  
F6C  C2B  C3B  DOUB  N  N   49  
F6C  C2C  C3C  SING  Y  N   50  
F6C  C2D  C3D  DOUB  N  N   51  
F6C  C3   C4   SING  N  N   52  
F6C  C3   C5   SING  N  N   53  
F6C  C3A  C4A  SING  N  N   54  
F6C  C3B  C4B  SING  N  N   55  
F6C  C3C  C4C  DOUB  Y  N   56  
F6C  C3D  C4D  SING  N  N   57  
F6C  C4C  NC   SING  Y  N   58  
F6C  C5   C6   SING  N  N   59  
F6C  C6   C7   SING  N  N   60  
F6C  C7   C8   SING  N  N   61  
F6C  C8   C9   SING  N  N   62  
F6C  C8   C10  SING  N  N   63  
F6C  C10  C11  SING  N  N   64  
F6C  C11  C12  SING  N  N   65  
F6C  C12  C13  SING  N  N   66  
F6C  C13  C14  SING  N  N   67  
F6C  C13  C15  SING  N  N   68  
F6C  NC   MG   SING  N  N   69  
F6C  CAA  H1   SING  N  N   70  
F6C  CAA  H2   SING  N  N   71  
F6C  CAB  H3   SING  N  N   72  
F6C  CAC  H4   SING  N  N   73  
F6C  CAC  H5   SING  N  N   74  
F6C  CBA  H6   SING  N  N   75  
F6C  CBA  H7   SING  N  N   76  
F6C  CBB  H8   SING  N  N   77  
F6C  CBB  H9   SING  N  N   78  
F6C  CBC  H10  SING  N  N   79  
F6C  CBC  H11  SING  N  N   80  
F6C  CBC  H12  SING  N  N   81  
F6C  CBD  H13  SING  N  N   82  
F6C  CED  H14  SING  N  N   83  
F6C  CED  H15  SING  N  N   84  
F6C  CED  H16  SING  N  N   85  
F6C  CHB  H17  SING  N  N   86  
F6C  CHC  H18  SING  N  N   87  
F6C  CHD  H19  SING  N  N   88  
F6C  CMA  H20  SING  N  N   89  
F6C  CMA  H21  SING  N  N   90  
F6C  CMA  H22  SING  N  N   91  
F6C  CMB  H23  SING  N  N   92  
F6C  CMC  H24  SING  N  N   93  
F6C  CMC  H25  SING  N  N   94  
F6C  CMC  H26  SING  N  N   95  
F6C  CMD  H27  SING  N  N   96  
F6C  CMD  H28  SING  N  N   97  
F6C  CMD  H29  SING  N  N   98  
F6C  C1   H30  SING  N  N   99  
F6C  C1   H31  SING  N  N  100  
F6C  C2   H32  SING  N  N  101  
F6C  C4   H33  SING  N  N  102  
F6C  C4   H34  SING  N  N  103  
F6C  C4   H35  SING  N  N  104  
F6C  C5   H36  SING  N  N  105  
F6C  C5   H37  SING  N  N  106  
F6C  C6   H38  SING  N  N  107  
F6C  C6   H39  SING  N  N  108  
F6C  C7   H40  SING  N  N  109  
F6C  C7   H41  SING  N  N  110  
F6C  C8   H42  SING  N  N  111  
F6C  C9   H43  SING  N  N  112  
F6C  C9   H44  SING  N  N  113  
F6C  C9   H45  SING  N  N  114  
F6C  C10  H46  SING  N  N  115  
F6C  C10  H47  SING  N  N  116  
F6C  C11  H48  SING  N  N  117  
F6C  C11  H49  SING  N  N  118  
F6C  C12  H50  SING  N  N  119  
F6C  C12  H51  SING  N  N  120  
F6C  C13  H52  SING  N  N  121  
F6C  C14  H53  SING  N  N  122  
F6C  C14  H54  SING  N  N  123  
F6C  C14  H55  SING  N  N  124  
F6C  C15  H56  SING  N  N  125  
F6C  C15  H57  SING  N  N  126  
F6C  C15  C16  SING  N  N  127  
F6C  C16  C17  SING  N  N  128  
F6C  C17  C18  SING  N  N  129  
F6C  C18  C19  SING  N  N  130  
F6C  C18  C20  SING  N  N  131  
F6C  C16  H58  SING  N  N  132  
F6C  C16  H59  SING  N  N  133  
F6C  C17  H60  SING  N  N  134  
F6C  C17  H61  SING  N  N  135  
F6C  C18  H62  SING  N  N  136  
F6C  C19  H63  SING  N  N  137  
F6C  C19  H64  SING  N  N  138  
F6C  C19  H65  SING  N  N  139  
F6C  C20  H66  SING  N  N  140  
F6C  C20  H67  SING  N  N  141  
F6C  C20  H68  SING  N  N  142  
#   #
loop_
_pdbx_chem_comp_descriptor.comp_id
_pdbx_chem_comp_descriptor.type
_pdbx_chem_comp_descriptor.program
_pdbx_chem_comp_descriptor.program_version
_pdbx_chem_comp_descriptor.descriptor
F6C  SMILES            ACDLabs               12.01  "C(CC(=O)OC\C=C(/C)CCCC(C)CCCC(C)CCCC(C)C)C=9C=3N4C(=CC8=N5C(=Cc6c(C)c(CC)c7C=C1N(=C2C=3C(C(=O)C2=C1C)C(=O)OC)[Mg]45n67)C(/C=C)=C8C=O)C=9C"  
F6C  InChI             InChI                 1.03   "InChI=1S/C55H69N4O6.Mg/c1-12-38-35(8)42-27-46-39(13-2)41(30-60)47(57-46)28-43-36(9)40(52(58-43)50-51(55(63)64-11)54(62)49-37(10)44(59-53(49)50)29-45(38)56-42)23-24-48(61)65-26-25-34(7)22-16-21-33(6)20-15-19-32(5)18-14-17-31(3)4;/h13,25,27-33,51H,2,12,14-24,26H2,1,3-11H3,(H-,56,57,58,59,60,62);/q-1;+2/p-1/b34-25+,42-27-,43-28-,44-29-,45-29-,46-27-,47-28-,52-50-;/t32-,33-,51-;/m1./s1"  
F6C  InChIKey          InChI                 1.03   YUTLCKLMRUVWDE-FOFJUSMOSA-M  
F6C  SMILES_CANONICAL  CACTVS                3.385  "CCc1c(C)c2C=C3N=C(C=C4[N@@]5[Mg]n2c1C=C6N=C7C(=C5C(=C4C)CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@@H](C(=O)OC)C(=O)C7=C6C)C(=C3C=C)C=O"  
F6C  SMILES            CACTVS                3.385  "CCc1c(C)c2C=C3N=C(C=C4[N]5[Mg]n2c1C=C6N=C7C(=C5C(=C4C)CCC(=O)OCC=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C)[CH](C(=O)OC)C(=O)C7=C6C)C(=C3C=C)C=O"  
F6C  SMILES_CANONICAL  "OpenEye OEToolkits"  2.0.7  "CCc1c(c2n3c1C=C4C(=C5C(=O)[C@@H](C6=C7C(=C(C8=CC9=[N]([Mg]3(N87)[N]4=C65)C(=C2)C(=C9C=O)C=C)C)CCC(=O)OC/C=C(\C)/CCC[C@H](C)CCCC(C)CCCC(C)C)C(=O)OC)C)C"  
F6C  SMILES            "OpenEye OEToolkits"  2.0.7  "CCc1c(c2n3c1C=C4C(=C5C(=O)C(C6=C7C(=C(C8=CC9=[N]([Mg]3(N87)[N]4=C65)C(=C2)C(=C9C=O)C=C)C)CCC(=O)OCC=C(C)CCCC(C)CCCC(C)CCCC(C)C)C(=O)OC)C)C"  
#
_pdbx_chem_comp_identifier.comp_id          F6C
_pdbx_chem_comp_identifier.type             "SYSTEMATIC NAME"
_pdbx_chem_comp_identifier.program          ACDLabs
_pdbx_chem_comp_identifier.program_version  12.01
_pdbx_chem_comp_identifier.identifier       "[methyl 9-ethenyl-14-ethyl-8-formyl-4,13,18-trimethyl-20-oxo-3-{3-oxo-3-[(3,7,11,15-tetramethylhexadec-2-en-1-yl)oxy]propyl}-3,4,23,25-tetradehydro-24,26-dihydrophorbine-21-carboxylatato(2-)-kappa~4~N~23~,N~24~,N~25~,N~26~]magnesium"
#   #
loop_
_pdbx_chem_comp_audit.comp_id
_pdbx_chem_comp_audit.action_type
_pdbx_chem_comp_audit.date
_pdbx_chem_comp_audit.processing_site
F6C  "Create component"    2019-07-03  RCSB  
F6C  "Other modification"  2020-01-09  RCSB  
F6C  "Initial release"     2020-01-15  RCSB  
F6C  "Modify synonyms"     2021-03-13  RCSB  
#
_pdbx_chem_comp_synonyms.ordinal     1
_pdbx_chem_comp_synonyms.comp_id     F6C
_pdbx_chem_comp_synonyms.name        "[methyl 9-ethenyl-14-ethyl-8-formyl-4,13,18-trimethyl-20-oxo-3-{3-oxo-3-[(3,7,11,15-tetramethylhexadec-2-en-1-yl)oxy]propyl}-3,4,23,25-tetradehydro-24,26-dihydrophorbine-21-carboxylatato(2-)-kappa~4~N~23~,N~24~,N~25~,N~26~]magnesium"
_pdbx_chem_comp_synonyms.provenance  PDB
_pdbx_chem_comp_synonyms.type        ?
##
